b)dd B là H₂SO₄ dư

số mol h2so4 là:

n_H2SO4(dư) = 0,1 - 0,02 = 0,08 mol

Nồng độ phần trăm dd B là :

C%_H2SO4 =\(\dfrac{0,08.98}{50+200-4,66}.100\%\)3,2 %

a) \(n_{H_2SO_4}=\dfrac{50.19,6}{100.98}=0,1\left(mol\right)\)

\(n_{Ba\left(OH\right)_2}=\dfrac{200.17,1}{100.171}=0,2\left(mol\right)\)

PTHH: Ba(OH)₂ + H₂SO₄ --> BaSO₄ + 2H₂O

Xét \(\dfrac{0,1}{1}< \dfrac{0,2}{1}\) => Ba(OH)₂ dư, H₂SO₄ hết

PTHH: Ba(OH)₂ + H₂SO₄ --> BaSO₄ + 2H₂O

_______0,1<-----0,1--------->0,1

=> m_BaSO4 = 0,1.233 = 23,3 (g) 

b) m_{dd sau pư} = 50 + 200 - 23,3 = 226,7 (g)

=> \(C\%=\dfrac{\left(0,2-0,1\right).171}{226,7}.100\%=7,543\%\)

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\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,3mol        0,6mol                                        0,3mol

\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)

\(n_{Na_2SO_4}=\dfrac{142.10}{100.142}=0,1(mol)\\ Na_2SO_4+Ba(OH)_2\to BaSO_4\downarrow+2NaOH\\ \Rightarrow n_{BaSO_4}=n_{Ba(OH)_2}=0,1(mol);n_{NaOH}=0,2(mol)\\ a,m_{BaSO_4}=0,1.233=23,3(g)\\ b,m_{dd_{Ba(OH)_2}}=\dfrac{0,1.171}{15\%}=114(g)\\ c,C\%_{NaOH}=\dfrac{0,2.40}{142+114-23,3}.100\%=3,44\%\)

Ta có: \(n_{Na_2SO_4}=\dfrac{\dfrac{10\%.142}{100\%}}{142}=0,1\left(mol\right)\)

\(PTHH:Na_2SO_4+Ba\left(OH\right)_2--->BaSO_4\downarrow+2NaOH\)

a. Theo PT: \(n_{BaSO_4}=n_{Ba\left(OH\right)_2}=n_{Na_2SO_4}=0,1\left(mol\right)\)

\(\Rightarrow m_{BaSO_4}=0,1.233=23,3\left(g\right)\)

b. Ta có: \(m_{Ba\left(OH\right)_2}=0,1.171=17,1\left(g\right)\)

Mà: \(C_{\%_{Ba\left(OH\right)_2}}=\dfrac{17,1}{m_{dd_{Ba\left(OH\right)_2}}}.100\%=15\%\)

\(\Leftrightarrow m_{dd_{Ba\left(OH\right)_2}}=114\left(g\right)\)

c. Ta có: \(m_{dd_{NaOH}}=114+14,2-23,3=104,9\left(g\right)\)

Theo PT: \(n_{NaOH}=2.n_{Ba\left(OH\right)_2}=2.0,1=0,2\left(mol\right)\)

\(\Rightarrow m_{NaOH}=0,2.40=8\left(g\right)\)

\(\Rightarrow C_{\%_{NaOH}}=\dfrac{8}{104,9}.100\%=7,63\%\)

a/

\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)

\(Na_2O+H_2O\rightarrow2NaOH\)

0,15 0,3 (mol)

\(m_{NaOH}=0,3.40=12\left(g\right)\)

\(m_A=90,7+9,3=100\left(g\right)\)

\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)

b/

m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)

\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)

\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)

bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)

pư: 0,3 0,15 0,15 0,15 (mol)

dư: 0 \(\dfrac{23}{380}\) (mol)

\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)

\(m_C=100+200-13,5=286,5\left(g\right)\)

\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)

\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)

\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)

\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)

Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)

\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

Dung dịch A gồm: CuSO₄ và H₂SO₄ dư

\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?

\(a,\left\{{}\begin{matrix}m_{BaCl_2}=\dfrac{100\cdot10,4\%}{100\%}=10,4\left(g\right)\\m_{H_2SO_4}=\dfrac{200\cdot9,8\%}{100\%}=19,6\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{BaCl_2}=\dfrac{10,4}{208}=0,05\left(mol\right)\\n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\end{matrix}\right.\)

\(PTHH:BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)

Vì \(\dfrac{n_{BaCl_2}}{1}< \dfrac{n_{H_2SO_4}}{2}\) nên \(H_2SO_4\) dư

\(\Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,05\left(mol\right)\\ \Rightarrow m_{BaSO_4}=0,05\cdot233=11,65\left(g\right)\)

\(b,n_{HCl}=n_{BaSO_4}=0,05\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,05\cdot36,5=1,825\left(g\right)\\ \Rightarrow m_{dd_{HCl}}=100+200-11,65=288,35\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{1,825}{288,35}\cdot100\%\approx0,63\%\)

Đáp án A

→ a =   0 , 0325